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Photo resist

1. DisCharge H2O, H2OX2, H2OX4 conductive layer
ㆍ  Improved Scanning Electron Microscope Imaging on Non-Conductive Substrate
ㆍ  * DisCharge H2O: about 40 nm @ 1000 RPM / Resistivity about 7.30 Ωm (Av.).
ㆍ  * DisCharge H2OX2: about 80 nm @ 1000 RPM / Resistivity about 7.65 Ωm (Av.).
ㆍ  * DisCharge H2OX4: about 165 nm @ 1000 RPM / Resistivity about 9.48 Ωm (Av.).
ㆍ  높은 안정성과 긴 제품 수명 (약 2년).
ㆍ  저렴한 가격. 25 ml ~ 4 L 다양한 용량.
DisCharge H2O, H2OX2, H2OX4 conductive layer
DisCharge H2O Advantage
DisCharge H2O Properties
  - Efficient charge dissipation in EBL on a broad range of resist
   materials (PMMA, HSQ, H-SiQ, mr-PosEBR, CSAR 62, ZEP 520A,
   SML).
  - Improved shape fidelity and positional accuracy of EBL patterns
   in resist on insulated substrate materials such as SiO2,
   fused silica, quartz, PDMS, etc.
  - Water based formulation with excellent wetting properties.
  - Simple spin coat application.
  - Easy residue free removal by water or IPA rinse.
  - Improved Scanning Electron Microscope Imaging on
   Non-Conductive Substrate.
  - 2 year shelf life at room temperature. Highly stable permanently
   charged non-polymer formulation. No filtration required prior
   to use.
       
 Product nameDisCharge H2ODisCharge H2OX2DisCharge H2OX4
 Solvent baseWaterWaterWater
 Film Thickness20 - 40 nm40 - 80 nm85 - 165 nm
 Resistivity
 (Averaged)
7.30 Ωm7.65 Ωm9.48 Ωm
 Shelf Life
 (at RT)
2 years2 years2 years

Spin Curves
Sheet Resistance vs Thickness
Spin_curves.jpg
DC_sheet_resistance.jpg

Evidence of DisCharge H2O Anti-Charging Properties
300 nm PMMA 950 A4 / 1 mm PDMS / bulk Si
Test1.jpg
Without DisCharge: charge accumulation and sudden charge dissipation caused by exceeding the dielectric breakdown strength of the PDMS to the Si substrate resulting in significant cracking of the resist.
Test1_1.jpg
WITH DisCharge: no charge accumulation, resulting in expected image with no harm to the PDMS.
   
 
300 nm SML300 on glass Slide
SML without DisCharge.jpg
Without DisCharge H2OX2: charge accumation leading to poor shape fidelity of the contrast curve pattern.   
SML with DisCharge.jpg




WITH DisCharge H2OX2: no charge accumulation is observed. The structure appears as expected.
300 nm mr-PosEBR on Glass Slide
Test2.jpg
Without DisCharge: charge accumation leading to poor shape fidelity of the contrast curve pattern.
 
Test2_1.jpg
WITH DisCharge: no charge accumulation is observed. The structure appears as expected. Crosslinking of the positive resist is especially observed at high doses.
200 nm ZEP520A on Glass Slide
Test3.jpg
Without DisCharge: charge accumation leading to poor shape fidelity of the contrast curve pattern.
 
Test3_1.jpg
WITH DisCharge: no charge accumulation is observed. The structure appears as expected. Crosslinking of the ZEP520A resist is especially observed at high doses.
300 nm CSAR 62 on Glass Slide
Test4.jpg
Without DisCharge: charge accumation leading to poor shape fidelity of the contrast curve pattern.
 
Test4_1.jpg
WITH DisCharge: no charge accumulation is observed. The structure appears as expected. Crosslinking of the CSAR62 resist is especially observed at high doses.
300 nm ZEP520A on Fused Silica
Test5.jpg
Without DisCharge: charge accumulation resulting in poor shape fidelity of the tower pattern.
Test5_1.jpg
WITH DisCharge: No charge accumulation is observed. The structures appear as expected.
Test6.jpg
Without DisCharge: charge accumulation resulting in poor shape fidelity of the tower pattern
Test6_1.jpg
WITH DisCharge: No charge accumulation is observed. The structures appear as expected.

Improved Scanning Electron Microscope Imaging on Non-Conductive Substrate
DisCharge can significantly improve SEM imaging of insulated substrates by providing a removable, non-destructive film, conductive film for enhanced resolution on contrast. DisCharge H2O X4 is recommended.
Test1.jpg
Test1_1.jpg
SML without DisCharge.jpg
Without DisCharge H2O: Low resolution and poor contrast.
SML with DisCharge.jpg
WITH DisCharge H2O: Greatly increase contrast and resolution.
Products Guide
Tone
Product (link)
Film Thickness (nm)
Feature
Adhesion PromoterSurPass seriesNAApply resist: Novolac, DNQ, PMMA, HSQ, PMGI, SU-8, SML, PI, ...
Negative ebeam resistHSQ series8 – 1,650Dilution: 1 - 45%.
Supply: Powder, Solution.
H-SiQ series25 – 850Dilution: 2 - 20%.
Supply: Powder, Solution.
AR-N 7520 New series100 – 800Best resolution: 28 nm.
e-beam, DUV, i-line.
Positive ebeam resistHARP PMMA series50  – 3,700m/W: 950K, 495K.
Dilution: 2 - 11 %.
HARP-C Copolymer series150  – 1,100MMA/MAA Copolyer.
  Dilution: 6 - 12 %.
PMMA series40  – 7,000m/W: 950K, 495K, 350K, 120K, 35K.
  Dilution: 1 - 18 %.
Copolymer series100  – 1,100Copolymer.
  Dilution: 1 - 13 %.
SML series50  – 4,800High resolution: 5 nm. Aspect ratio: >50:1.
  Slow etch rate.
Conductive layerDisCharge H2O series25 – 170Apply resist: PMMA, HSQ, mr-PosEBR, AR-P 6200, ZEP, SML.
Protective Surface CoatingPSC-10032.4 – 5.3Protective Surface Coating
PSC-IB DPM 101010 (@ 2000 RPM)Protective Surface Coating
* Double coating.